Acta Univ. Agric. Silvic. Mendelianae Brun. 2016, 64(5), 1459-1464 | DOI: 10.11118/actaun201664051459
Electroless Deposition of Ni-P/SiO2 Composite Coating
- 1 Brno University of Technology, Faculty of Chemistry, Purkyňova 464/118, 602 00 Brno, Czech Republic
- 2 Fosfa a.s., Hraniční 268/120, Poštorná, 691 41 Břeclav, Czech Republic
Electroless deposit Ni-P/SiO2 composite coating was performed on the steel substrate, DIN EN 10130. The preparation of nickel coating included two main steps. In the first step, the fraction of SiO2 particles sized the tens of nanometres was obtained by sedimentation. In the second step, the composite coating was plated on the steel substrate. The actual deposition process contains the deposition of plain Ni-P interlayer which served as the nucleation center for the deposition of Ni-P/SiO2 composite coating with co-deposited SiO2 particles. The morphology of deposited composite coating was studied by scanning electron microscope (SEM). Amount of individual elements in deposited coatings was determinated by EDS analysis. The microhardness of deposited composite coating was subsequently compared with microhardness value of the plain Ni-P coating.
Keywords: EDS analysis, electroless deposition, Ni-P coating, Ni-P/SiO2 composite coating, steel substrate DIN EN 10130
Grants and funding:
This work was supported by project Nr. LO1211, Materials Research Centreat FCH BUT - Sustainability and Development (National Programme for Sustainability I, Ministry of Education, Youth and Sports).
Prepublished online: October 30, 2016; Published: November 1, 2016 Show citation
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References
- RIEDEL, W. 1991. Electroless Nickel Plating. Ohio: ASTM INTERNATIONAL Metals Park.
- BUCHTÍK, M. 2014. Nickel coatings and their properties. [in Czech: Niklové povlaky a jejich vlastnosti]. Brno: Brno University of Technology. Available at: www.vutbr.cz/www_base/zav_prace_soubor_verejne.php?file_id=83039.
- DE HAZAN, Y., ZIMMERMANN, D., Z'GRAGGEN, M. et al. 2010. Homogeneous electroless Ni-P/SiO2 nanocomposite coatings with improved wear resistance and modified wear behavior. Surface and Coatings Technology, 204: 3464 - 3470. Available at: http://veralit.ch/pdf/Surface_and_Coating_Technology.pdf. DOI: 10.1016/j.surfcoat.2010.04.007
Go to original source...
- RABIZADEH, T., ALLAHKARAM. S. R. 2011. Corrosion resistance enhancement of Ni-P electroless coatings by incorporation of nano-SiO2 particles. [Online]. Materials & Design, 32(1): 133 - 138. Available at: http://www.sciencedirect.com/science/article/pii/S0261306910003961. [cit. 2016-02-29]. DOI: 10.1016/j.matdes.2010.06.021
Go to original source...
- DONG, D., CHEN, X. H., XIAO, W. T., et al. 2009. Preparation and properties of electroless Ni-P-SiO2 composite coatings. [Online]. Applied Surface Science, 255(15): 7051 - 7055. Available at: http://www.sciencedirect.com/science/article/pii/S0169433209003055. [cit. 2016-02-29]. DOI: 10.1016/j.apsusc.2009.03.039
Go to original source...
- LI, CH., WANG, Y., PAN, Z. 2013. Wear resistance enhancement of electroless nanocomposite coatings via incorporation of alumina nanoparticles prepared by milling. [Online]. Materials & Design, 47: 443 - 448. Available at: http://www.sciencedirect.com/science/article/pii/S0261306912008424. [cit. 2016-02-29]. DOI: 10.1016/j.matdes.2012.12.021
Go to original source...
- GEORZIGA, E., NOVAKOVIC, J., VASSILIOU, P. 2013. Characterization and corrosion resistance of duplex electroless Ni-P composite coatings on magnesium alloy. [Online]. Surface and Coatings Technology, 232: 432 - 439. ISSN 02578972. Available at: http://www.sciencedirect.com/science/article/pii/S025789721300491X. [cit. 2016-02-29]. DOI: 10.1016/j.surfcoat.2013.05.047
Go to original source...
- FARZANEH, A., MOHAMMADI, M., EHTESHAMZADEH, M. et al. 2013. Electrochemical and structural properties of electroless Ni-P-SiC nanocomposite coatings. [Online]. Applied Surface Science, 276: 697 - 704. Available at: http://www.sciencedirect.com/science/article/pii/S0169433213006545. [cit. 2016-02-29]. DOI: 10.1016/j.apsusc.2013.03.156
Go to original source...
- MALLORY, G. O., HAJDU, J. B. 1990. Electroless Plating - Fundamentals and Applications. Orlando: William Andrew Publishing/Noyes.
- HU, B., SUN, R., YU, G. et al. 2013. Effect of bath pH and stabilizer on electroless nickel plating of magnesium alloys. [Online]. Surface and Coatings Technology, 228, 84 - 91. Available at: http://www.sciencedirect.com/science/article/pii/S0257897213003435. [cit. 2016-02-29]. DOI: 10.1016/j.surfcoat.2013.04.011
Go to original source...
- SHAO, Z., CAI, Z., HU, R. et al. 2014. The study of electroless nickel plating directly on magnesium alloy. [Online]. Surface and Coatings Technology, 249: 42 - 47. [cit. 2016-02-29]. Available at: http://www.sciencedirect.com/science/article/pii/S0257897214002606. DOI: 10.1016/j.surfcoat.2014.03.043
Go to original source...
- ELCHEMCO. c2016. Electroless nickel coating - characteristic. [Online]. Available at: http://web.elchemco.cz/niklovani.php.
- CAVALLOTTI, P., SALVAGO, G. 1968. Studies on chemical reduction of nickel and cobalt by hypophosphite II. Characteristics of the process. Electrochimica Metallorum, 3: 239 - 266.
- BIELINSKI, J. 1984. Untersuchugen zur Optinierugn von Loesunger zur chemischen Vernickeling. Metalloberfläche, 38: 20 - 26.
- BRHEL, D. c2016. Marking steel DIN - EN - ČSN [In Czech: Značení ocelí DIN - EN - ČSN]. Available at: http://www.salzgitter.cz/index.php?page=33.
- KOSÁR, P. 2013. Nickel coatings of magnesium alloys. [In Czech: Niklové povlaky hořčíkových slitin]. Brno University of technology.
- LUDVÍK, J., BÍLEK, K., LUDVÍK, Š. 2010. Hardness tests: Basic test methods for users of microhardness testers Qness [In Czech: Zkoušky tvrdosti: Základní testovací metody pro uživatele mikrotvrdoměrů]. Available at: http://www.metrotest.cz/files/zkousky_tvrdosti.pdf.
- ASTM INTERNATIONAL. 2007. ASTM E10-07a Standard Test Method for Brinell Hardness of Metallic Materials. Philadelphia: ASTM International.
- NOVAKOVIC, J., VASSILLIOU, P., SAMARA, K. et al. 2006. Electroless NiP - TiO2 composite coatings: Their production and properties. [Online]. Surface and Coatings Technology, 201(3 - 4): 895 - 901. Available at: http://www.sciencedirect.com/science/article/pii/S0257897206000351. [cit. 2016-02-29]. DOI: 10.1016/j.surfcoat.2006.01.005
Go to original source...
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